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On-Surface Synthesis of Polypyridine: Strain Enforces Extended Linear Chains

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Patera, Laerte L. ; Amler, Josef ; Repp, Jascha
License: Creative Commons Attribution 4.0
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Date of publication of this fulltext: 07 Mar 2022 14:14


Strain-induced on-surface transformations provide an appealing route to steer the selectivity towards desired products. Here, we demonstrate the selective on-surface synthesis of extended all-trans poly(2,6-pyridine) chains on Au(111). By combining high-resolution scanning tunneling and atomic force microscopy, we revealed the detailed chemical structure of the reaction products. Density ...


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