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On-Surface Synthesis of Polypyridine: Strain Enforces Extended Linear Chains

URN to cite this document:
urn:nbn:de:bvb:355-epub-516970
DOI to cite this document:
10.5283/epub.51697
Patera, Laerte L. ; Amler, Josef ; Repp, Jascha
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License: Creative Commons Attribution 4.0
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Date of publication of this fulltext: 07 Mar 2022 14:14



Abstract

Strain-induced on-surface transformations provide an appealing route to steer the selectivity towards desired products. Here, we demonstrate the selective on-surface synthesis of extended all-trans poly(2,6-pyridine) chains on Au(111). By combining high-resolution scanning tunneling and atomic force microscopy, we revealed the detailed chemical structure of the reaction products. Density ...

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