Three‐Component Self‐Assembly Changes its Course: A Leap from Simple Polymers to 3D Networks of Spherical Host–Guest Assemblies.
Die Dreikomponenten-Selbstorganisation ändert ihre Richtung: Ein Sprung von einfachen Polymeren zu 3D-Netzwerken sphärischer Wirt/Gast-Aggregate

URN to cite this document:

urn:nbn:de:bvb:355-epub-525045 Copy

DOI to cite this document:

10.5283/epub.52504 Copy

Peresypkina, Eugenia V. ; Grill, Kevin ; Hiltl, Barbara ; Virovets, Alexander V. ; Kremer, Werner ; Hilgert, Jan ; Tremel, Wolfgang ; Scheer, Manfred

Preview	License: Creative Commons Attribution Non-commercial No Derivatives 4.0 PDF - Published Version (3MB)
Preview	License: Creative Commons Attribution Non-commercial No Derivatives 4.0 PDF - Published Version (3MB)

Date of publication of this fulltext: 24 Jun 2022 12:48

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This publication is part of the DEAL contract with Wiley.

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Details

Item type:	Article
Open Access Type:	DEAL (Wiley)
Journal or Publication Title:	Angewandte Chemie International Edition
Publisher:	Wiley
Place of Publication:	WEINHEIM
Volume:	60
Number of Issue or Book Chapter:	21
Page Range:	pp. 12132-12142
Date:	8 March 2021
Institutions:	Biology, Preclinical Medicine > Institut für Biophysik und physikalische Biochemie Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Projects:	Sphärische Riesenmoleküle mit inneren und äußeren Funktionalitäten Funded by: Deutsche Forschungsgemeinschaft (DFG) (456387018)
Identification Number:	Value Type 10.1002/anie.202103178 DOI 10.1002/ange.202103178 DOI
Keywords:	coordination networks; flexible linkers; metallosupramolecular chemistry; pentaphosphaferrocene; supramolecules
Dewey Decimal Classification:	500 Science > 540 Chemistry & allied sciences 500 Science > 570 Life sciences
Status:	Published
Refereed:	Yes, this version has been refereed
Created at the University of Regensburg:	Yes
Item ID:	52504

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Abstract

One-pot self-assembly reactions of the polyphosphorus complex [Cp*Fe(eta(5)-P-5)] (A), a coinage metal salt AgSbF6, and flexible aliphatic dinitriles NC(CH2)(x)CN (x=1-10) yield 1D, 2D, and 3D coordination polymers. The seven-membered backbone of the dinitrile was experimentally found as the borderline for the self-assembly system furnishing products of different kinds. At x<7, various rather ...

Abstract

One-pot self-assembly reactions of the polyphosphorus complex [Cp*Fe(eta(5)-P-5)] (A), a coinage metal salt AgSbF6, and flexible aliphatic dinitriles NC(CH2)(x)CN (x=1-10) yield 1D, 2D, and 3D coordination polymers. The seven-membered backbone of the dinitrile was experimentally found as the borderline for the self-assembly system furnishing products of different kinds. At x<7, various rather simple polymers are exclusively formed possessing either 0D or 1D Ag/A structural motifs connected by dinitrile spacers, while at x >= 7, the self-assembly switches to unprecedented extraordinary 3D networks of nano-sized host-guest assemblies (SbF6)@[(A)(9)Ag-11](11+) (x=7) or (A)@[(A)(12)Ag-12](12+) (x=8-10) linked by dinitriles. The polycationic nodes represent the first superspheres based on A and silver and are host-guest able. All products are characterized by NMR spectroscopy, mass spectrometry, and single-crystal X-ray diffraction. The assemblies [(A)(12)Ag-12](12+) were visualized by transmission electron microscopy.

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Metadata last modified: 27 Mar 2025 07:39

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