Go to content
UR Home

Halogenation and Nucleophilic Quenching: Two Routes to E−X Bond Formation in Cobalt Triple‐Decker Complexes (E=As, P; X=F, Cl, Br, I)

URN to cite this document:
urn:nbn:de:bvb:355-epub-527302
DOI to cite this document:
10.5283/epub.52730
Garbagnati, Anna ; Piesch, Martin ; Seidl, Michael ; Balázs, Gábor ; Scheer, Manfred
Date of publication of this fulltext: 09 Aug 2022 04:27

This publication is part of the DEAL contract with Wiley.


Abstract

The oxidation of [(Cp'''Co)(2)(mu,eta(2) : eta(2)-E-2)(2)] (E = As (1), P (2); Cp''' = 1,2,4-tri(tert-butyl)cyclopentadienyl) with halogens or halogen sources (I-2, PBr5, PCl5) was investigated. For the arsenic derivative, the ionic compounds [(Cp'''Co)(2)(mu,eta(4) : eta(4)-As4X)][Y] (X = I, Y = [As(6)I8](0.5) (3 a), Y = [Co2Cl6-nIn](0.5 )(n = 0, 2, 4; 3 b); X = Br, Y = [Co2Br6](0.5) (4); X = ...

plus


Owner only: item control page
  1. Homepage UR

University Library

Publication Server

Contact:

Publishing: oa@ur.de
0941 943 -4239 or -69394

Dissertations: dissertationen@ur.de
0941 943 -3904

Research data: datahub@ur.de
0941 943 -5707

Contact persons