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Hybrid Catalysts for Enantioselective Photo-Phosphoric Acid Catalysis

Rolka, Alessa B. ; Archipowa, Nataliya ; Kutta, Roger Jan ; König, Burkhard ; Toste, F. Dean


The syntheses of two novel, organic, and chiral photocatalysts are presented. By combining donor–acceptor cyanoarene-based photocatalysts with a chiral phosphoric acid, bifunctional catalysts have been designed. In preliminary proof-of-concept reactions, their use in both enantioselective energy transfer and photoredox catalysis is demonstrated.

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