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On the Brink of Decomposition: Controlled Oxidation of a Substituted Arsanylborane as a Way to Labile Group 13‐15‐16 Compounds

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Lehnfeld, Felix ; Seidl, Michael ; Timoshkin, Alexey Y. ; Scheer, Manfred
Date of publication of this fulltext: 07 Aug 2023 14:45

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The reactivity of the organic-substituted arsanylborane tBuAsHBH2NMe3 (1) towards different elemental chalcogenes as well as organic oxidants such as O-NMe3, Me3Si−O−O-SiMe3, MesCNO and cyclohexenesulfide is reported. By the reaction of 1 with grey selenium, the selenium oxidation product tBuAs(Se)HBH2NMe3 (2) was obtained. For the oxidation with sulfur, the two products tBuAs(S)HBH2NMe3 (3 a) ...


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