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- URN zum Zitieren dieses Dokuments:
- urn:nbn:de:bvb:355-epub-552632
- DOI zum Zitieren dieses Dokuments:
- 10.5283/epub.55263
Zusammenfassung
The reaction behavior of [Cp*Fe(η5-As5)] (I) (Cp*=C5Me5) towards carbenes and their heavier analogs was investigated. The reaction of I with NHCs (NHCs=N-heterocyclic carbenes) results in the first substitution products of polyarsenic ligand complexes by NHCs [Cp*Fe(η4-As5NHC)] (1 a: NHC=IMe=1,3,4,5-tetramethylimidazolin-2-ylidene, 1 b: ...
