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Cu(I) Complexes Comprising tetrahedral Mo2E2 or Mo2PE units (E=P, As, Sb) as Chelating Ligands

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Mondal, Bijan ; Scheer, Manfred
Date of publication of this fulltext: 18 Jan 2024 06:27

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Novel isomorphous tetranuclear complexes, [(dppf)Cu(μ3,η2 : 2 : 2-E2{CpMo(CO)2}2]BF4 [E=P (1), As (4), Sb (5), (dppf=1,1′-bis-(diphenylphosphino)-ferrocene)] and [(dppf)Cu(μ3,η2 : 2 : 2-PE{CpMo(CO)2}2]BF4 [E=As (2), Sb(3)] were synthesized from the reactions between [(dppf)Cu(MeCN)2][BF4] and tetrahedral molybdenum complexes containing unsubstituted homo- and hetero-diatomic group-15 elements ...


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