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Au-Containing Coordination Polymers Based on Polyphosphorus Ligand Complexes

Brake, Helena ; Peresypkina, Eugenia ; Virovets, Alexander V. ; Kremer, Werner ; Klimas, Christian ; Schwarzmaier, Christoph ; Scheer, Manfred



Abstract

Whereas the self-assembly of pentaphosphaferrocenes [(CpFe)-Fe-R(eta(5)-P-5)] (Cp-R = Cp*, Cp-x, and Cp-Bn) with Cu and Ag salts has been well-studied in the past, the coordination chemistry toward Au complexes has been left untouched so far. Herein, the results of the self-assembly processes of [(CpFe)-Fe-R(eta(5)-P-5)] with Au salts of different anions (GaCl4-, SbF6-, and Al(OC(CF3)(3))(4) ...

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