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Reactivity of Cu(I) Nacnac Complexes Toward Polypnictogen Compounds

Haimerl, Maria ; Piesch, Martin ; Balázs, Gábor ; Mastrorilli, Piero ; Kremer, Werner ; Scheer, Manfred



Abstract

The nacnac Cu(I) compound [LCu(MeCN)] (2) (L = [{N(C6H3Me2-2,6)C(Me)}(2)CH](-)) was reacted with complexes containing aromatic cyclo-E-5 ([Cp*Fe(eta(5)-E-5)], E = P (1a), As (1b), Cp* = eta(5)-C5Me5), cyclo-P-4 ([Cp'''Co(eta(4)-P-4)] (3), Cp''' = eta(5)-(C5H2Bu3)-Bu-t) and cyclo-E-3 ligands ([Cp'''Ni(eta(3)-E-3)], E = P (4a), As (4b)) yielding the heterometallic complexes ...

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