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Coordination Chemistry of Anionic Pnictogenylborane Compounds

Elsayed Moussa, Mehdi ; Kahoun, Tobias ; Ackermann, Matthias T. ; Seidl, Michael ; Bodensteiner, Michael ; Timoshkin, Alexey Y. ; Scheer, Manfred



Abstract

Novel anionic metallacycles (6: [(1) W(CO)(4)]; 7: ([(2) W(CO)(4)])(2); 8: [(3) W(CO)(4)]; 9: [(4) W(CO)(4)]; and 10: [(5) W(CO)(4)]) were selectively synthesized from the reaction of the flexible anionic pnictogenylborane derivatives [M(C12H24O6)][H2E-BH2-EH2] [E = P, M = Na (1); E = As, M = K (2)], [Na(C12H24O6)][H2As-BH2-PH2-BH2-AsH2] (3), and [Na(C12H24O6)(thf)2][tBuHE-BH2-EHtBu] [E = P (4); ...

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