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Discrete Polymetallic Arrangements of AgI and CuI Ions Based on Multiple Bridging Phosphane Ligands and π–π Interactions

Attenberger, Bianca ; El Sayed Moussa, Mehdi ; Brietzke, Thomas ; Vreshch, Volodimir ; Holdt, Hans‐Jürgen ; Lescop, Christophe ; Scheer, Manfred



Zusammenfassung

A simple and straightforward approach to new polymetallic Ag-I and Cu-I supramolecules is presented. The reaction of N,P,N,P,N ligand 2 with Ag-I ions affords a trimetallic complex bearing a triangular Ag-3 core; metallophilic interactions are stabilized by ligands that display a multiple bridging coordination mode as 10-electron donors. Heteroleptic polymetallic Ag-I and Cu-I complexes based on ...

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