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Chemoselective Crossed Acyloin Condensations: Catalyst and Substrate Control

Zeitler, Kirsten ; Connon, Stephen ; Rose, Christopher ; Gundala, Sivaji



Zusammenfassung

The interplay between catalyst and substrate control in crossed acyloin condensation reactions has been studied. It was found that a pentafluorophenyl-substituted triazolium ion derived catalyst was capable of catalyzing highly chemoselective processes between a range of aliphatic and aromatic aldehydes utilized in a 1:1 ratio.


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