Zusammenfassung
The formation of a new type of organometallic-inorganic hybrid coordination polymer from P4S3 center dot W(CO)(5) (1) and CuI has been studied. The structure of (P4S3 center dot W(CO)(5)}(CuI) (3) has been verified by the combination of spectroscopic (IR, Raman, P-31 MAS NMR) and X-ray diffraction methods. Theoretical studies of beta-P4S3, P4S3 center dot W(CO)(5) (1), 1D-(P4S3)(CuI) (2), and ...
Zusammenfassung
The formation of a new type of organometallic-inorganic hybrid coordination polymer from P4S3 center dot W(CO)(5) (1) and CuI has been studied. The structure of (P4S3 center dot W(CO)(5)}(CuI) (3) has been verified by the combination of spectroscopic (IR, Raman, P-31 MAS NMR) and X-ray diffraction methods. Theoretical studies of beta-P4S3, P4S3 center dot W(CO)(5) (1), 1D-(P4S3)(CuI) (2), and 3D-(P4S3)(CuI)(3) (4), which may be considered as potential building blocks of 3, were carried out on the DFT level in the crystalline phase. The comparison of calculated and measured vibration modes of the P4S3 cage allows the unequivocal assignment of the recorded Raman shifts between 200 and 480 cm(-1) and the determination of the degree of integration of P4S3 within the one-dimensional stacks of 2 or copper iodide networks of 3 and 4.
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