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Substrate Polarization Alters the Jahn-Teller Effect in a Single Molecule

URN to cite this document:
urn:nbn:de:bvb:355-epub-766411
DOI to cite this document:
10.5283/epub.76641
Frankerl, Moritz ; Patera, Laerte L. ; Giselbrecht, Felix ; Frederiksen, Thomas ; Repp, Jascha ; Donarini, Andrea
[img]License: Creative Commons Attribution 4.0
PDF - Published Version
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Date of publication of this fulltext: 06 May 2025 06:12



Abstract

Charge-state transitions of a single Cu-phthalocyanine molecule adsorbed on an insulating layer of NaCl on Cu(111) are probed by means of alternate charging scanning tunneling microscopy. Real-space imaging of the electronic transitions reveals the Jahn-Teller distortion occurring upon formation of the first and second anionic charge states. The experimental findings are rationalized by a ...

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