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- URN zum Zitieren dieses Dokuments:
- urn:nbn:de:bvb:355-epub-784839
- DOI zum Zitieren dieses Dokuments:
- 10.5283/epub.78483
Zusammenfassung
Boron–ligand cooperation (BLC) has emerged as a powerful principle of bond activation with main-group elements, yet pyridine-based systems have so far eluded experimental evidence of CO2 activation. We show here that four-membered pyridyl–boracycles activate CO2 through a dearomatizing boron–carbon bond cleavage, unambiguously proceeding by a BLC rather than a B/N-FLP-type mechanism, as confirmed ...
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