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Functionalized derivatives of 1,4-dimethylnaphthalene as precursors for biomedical applications: synthesis, structures, spectroscopy and photochemical activation in the presence of dioxygen

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Posavec, Damir ; Zabel, Manfred ; Bogner, Udo ; Bernhardt, Günther ; Knör, Günther
License: Allianz- bzw. Nationallizenz
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Date of publication of this fulltext: 19 Aug 2014 06:22


Decomposition of endoperoxide containing molecules is an attractive approach for the delayed release of singlet oxygen under mild reaction conditions. Here we describe a new method for the adaptation of the corresponding decay times by controlling the supramolecular functional structure of the surrounding matrix in the immediate vicinity of embedded singlet oxygen precursors. Thus, a significant ...


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