Iodination of cyclo-E5-Complexes (E = P, As). Die Iodierung von cyclo‐E5‐Komplexen (E=P, As)

URN to cite this document:: urn:nbn:de:bvb:355-epub-445819
DOI to cite this document:: 10.5283/epub.44581

Brake, Helena ; Peresypkina, Eugenia V. ; Virovets, Alexander V. ; Piesch, Martin ; Kremer, Werner ; Zimmermann, Lisa ; Klimas, Christian ; Scheer, Manfred

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Date of publication of this fulltext: 25 Jan 2021 08:28

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Abstract

In a high-yield one-pot synthesis, the reactions of [Cp*M(eta(5)-P-5)] (M=Fe (1), Ru (2)) with I(2)resulted in the selective formation of [Cp*MP6I6](+)salts (3,4). The products comprise unprecedented all-cistripodal triphosphino-cyclotriphosphine ligands. The iodination of [Cp*Fe(eta(5)-As-5)] (6) gave, in addition to [Fe(CH3CN)(6)](2+)salts of the rare [As6I8](2-)(in7) and [As4I14](2-)(in8) ...