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- URN to cite this document:
- urn:nbn:de:bvb:355-epub-445819
- DOI to cite this document:
- 10.5283/epub.44581
Abstract
In a high-yield one-pot synthesis, the reactions of [Cp*M(eta(5)-P-5)] (M=Fe (1), Ru (2)) with I(2)resulted in the selective formation of [Cp*MP6I6](+)salts (3,4). The products comprise unprecedented all-cistripodal triphosphino-cyclotriphosphine ligands. The iodination of [Cp*Fe(eta(5)-As-5)] (6) gave, in addition to [Fe(CH3CN)(6)](2+)salts of the rare [As6I8](2-)(in7) and [As4I14](2-)(in8) ...

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