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Article

Neumeier, M. and Gschwind, R. M. (2014) Elongated Gilman Cuprates: The Key to Different Reactivities of Cyano- and Iodocuprates. Journal of the American Chemical Society 136 (15), pp. 5765-5772.

Schwarzmaier, C. and Schindler, A. and Heindl, C. and Scheuermayer, S. and Peresypkina, E. V. and Virovets, A. V. and Neumeier, M. and Gschwind, R. M. and Scheer, Manfred (2013) Stabilization of Tetrahedral P4 and As4 Molecules as Guests in Polymeric and Spherical Environments. Angewandte Chemie International Edition 52 (41), pp. 10896-10899.

Hartmann, E. and Hammer, M. M. and Gschwind, R. M. (2013) Structures and Interligand Interaction Pattern of Phosphoramidite Pd Complexes by NMR: Modulations in Extended Interaction Surfaces as Stereoselection Mode of a Privileged Class of Ligands. Chemistry - A European Journal 19 (32), pp. 10551-10562.

Schober, K. and Hartmann, E. and Zhang, H. and Gschwind, R. M. (2010) 1H DOSY Spectra of Ligands for Highly Enantioselective Reactions - A Fast and Simple NMR Method to Optimize Catalytic Reaction Conditions. Angew. Chem. Int. Ed. 49 (15), pp. 2794-2797.

Kleinmaier, R. and Gschwind, R. M. (2010) Chemical Shift Assignment and Conformational Analysis of Monoalkylated Acylguanidines. Magn. Reson. Chem. 48 (9), pp. 687-684.

Kleinmaier, R. and Igel, P. and Keller, M. and Buschauer, Armin and Gschwind, R. M. (2010) Conformations, Conformational Preferences, and Conformational Exchange of N'-Substituted N-Acylguanidines: Intermolecular Interactions Hold the Key. J. Am. Chem. Soc. 132 (32), pp. 11223-11233.

Thaler, T. and Haag, B. and Gavryushin, A. and Schober, K. and Hartmann, E. and Gschwind, R. M. and Zipse, H. and Mayer, P. and Knochel, P. (2010) Highly diastereoselective Csp3–Csp2 Nis cross-coupling with 1,2-, 1,3- and 1,4-substituted cyclokylzinc compounds. Nature Chemistry 2 (2), pp. 125-130.

Brandl, Ferdinand and Kastner, Fritz and Gschwind, R. M. and Blunk, Torsten and Teßmar, Jörg and Göpferich, Achim (2010) Hydrogel-based drug delivery systems: Comparison of drug diffusivity and release kinetics. Journal of Controlled Release 142 (2), pp. 221-228.

Gärtner, T. and Yoshikai, N. and Neumeier, M. and Nakamura, E. and Gschwind, R. M. (2010) Ligand exchange reactions in Cu(III) complexes: mechanistic insights by combined NMR and DFT studies. Chem. Commun. 46 (25), pp. 4625-4626.

Ay, S. and Ziegert, R. E. and Zhang, H. and Nieger, M. and Rissanen, K. and Fink, K. and Kubas, A. and Gschwind, R. M. and Bräse, S. (2010) NMR-Spectroscopic and Solid-State Investigations of Cometal-Free Asymmetric Conjugate Addition: A Dinuclear Paracyclophaneimine Zinc Methyl Complex. J. Am. Chem. Soc. 132 (37), pp. 12899-12905.

Gschwind, R. M. (2010) NMR-Spektroskopie (Trendberichte 2009, Organische Chemie). Nachrichten aus der Chemie 58, pp. 280-281.

Schmid, M. B. and Zeitler, K. and Gschwind, R. M. (2010) The elusive enamine intermediate in proline-catalyzed aldol reactions: NMR detection, formation pathway, and stabilization trends. Angew. Chem. Int. Ed. 49 (29), pp. 4997-5003.

Zhang, H. and Kerssebaum, R. and Gschwind, R. M. (2009) Improved applicability of DOSY experiments by high resolution probes combined with gradient amplifiers of diffusion units. Magnetic Resonance Chemistry 47 (7), pp. 568-572.

Gschwind, R. M. (2009) NMR-Spektroskopie (Trendberichte 2008, Organische Chemie). Nachrichten aus der Chemie 57, pp. 262-263.

Schmid, M. and Fleischmann, M. and D´Elia, V. and Reiser, O. and Gronwald, W. and Gschwind, R. M. (2009) RDCs in Short Peptidic Foldamers: Combined Analyses of Backbone and Side Chain Conformations and Evaluation of Structure Coordinates of Rigid Unnatural Amino Acids. ChemBioChem 10 (3), pp. 440-444.

Kleinmaier, R. and Gschwind, R. M. (2009) Selective [15N.eta.2] labelling of an NG-propionylated arginine derivative. Journal of Labelled Compounds and Radiopharmaceuticals 52 (2), pp. 29-32.

Dem’yanov, P. I. and Polestshuk, P. M. and Gschwind, R. M. (2008) Hydrogen-bonding interactions in monomeric dimethylcuprates. A theoretical study. Journal of Molecular Structure THEOCHEM 861 (1-3), pp. 85-96.

Gschwind, R. M. (2008) NMR-Spektroskopie (Trendberichte 2007, Organische Chemie). Nachrichten aus der Chemie 56, p. 283.

Henze, W. and Gärtner, T. and Gschwind, R. M. (2008) Organocuprate Conjugate Addition: The Structural Features of Diastereomeric and Supramolecular p-Intermediates. Journal of the American Chemical Society 130 (41), pp. 13718-13726.

Gschwind, R. M. (2008) Organocuprates and Diamagnetic Copper Complexes: Structures and NMR Spectroscopic Structure Elucidation in Solution. Chemical Reviews 108 (8), pp. 3029-3053.

Dem’yanov, P. I. and Polestshuk, P. M. and Petrosyan, V. S. and Gschwind, R. M. (2008) Structure of (Me2Cu)Li • 3DME and its oligomers [(Me2Cu)Li • 3DME]n (n = 2-5): a theoretical study. Russian Chemical Bulletin 57 (3), pp. 480-492.

Schober, K. and Zhang, H. and Gschwind, R. M. (2008) Temperature-Dependent Interconversion of Phosphoramidite-Cu Complexes Detected by Combined Diffusion Studies, 31P NMR, and Low-Temperature NMR Spectroscopy. Journal of the American Chemical Society 130 (37), pp. 12310-12317.

Federwisch, G. and Kleinmaier, R. and Drettwan, D. and Gschwind, R. M. (2008) The H-Bonding Network of Acylguanidine Complexes: Combined Intermolecular 2hJH,P and 3hJN,P Scalar Couplings Provide an Insight into the Geometric Arrangement. Journal of the American Chemical Society 130 (50), pp. 16846-16847.

Zhang, H. and Gschwind, R. M. (2007) Influence of Copper Salts, Solvents, and Ligands on the Structures of Precatalytic Phosphoramidite Copper Complexes for Conjugate Addition Reactions. Chemistry - A European Journal 13 (23), pp. 6691-6700.

Gärtner, T. and Henze, W. and Gschwind, R. M. (2007) NMR-Detection of Cu(III) Intermediates in Substitution Reactions of Alkyl Halides with Gilman Cuprates. Journal of the American Chemical Society 129 (37), pp. 11362-11363.

Gschwind, R. M. (2007) NMR-Spektroskopie (Trendberichte 2006, Organische Chemie). Nachrichten aus der Chemie 55, pp. 273-274.

Brandl, F. and Henke, M. and Rothschenk, S. and Gschwind, R. M. and Breunig, M. and Tessmar, J and Goepferich, A. (2007) Poly(ethylene glycol) based hydrogels for intraocular applications. Advanced Engineering Materials 9 (12), pp. 1141-1149.

Dem'yanov, P. I. and Gschwind, R. M. (2006) Formation of Hydrogen Bonds in Complexes between Dimethylcuprate(I) Anion and Methane, Propane, or Dimethyl Ether. A Theoretical Study. Organometallics 25 (24), pp. 5709-5723.

Gschwind, R. M. (2006) NMR-Spektroskopie (Trendberichte 2005, Organische Chemie). Nachrichten aus der Chemie 54, p. 252.

Zhang, H. and Gschwind, R. M. (2006) Structure Identification of Precatalytic Phosphoramidite Complexes in Solution. Angewandte Chemie International Edition 45 (38), pp. 6391-6394.

Raab, M. and Schick, G. and Fondermann, M. D. and Henze, W. and Weymand, U. and Gschwind, R. M. and Fischer, K. and Schmidt, M. and Niecke, E. (2006) The First PH-Functionalized Polyphosphazene: A Liquid Macromolecule with Highly Flexible Backbone. Angewandte Chemie International Edition 45 (19), pp. 3083-3086.

Ghosh, P. and Federwisch, G. and Kogey, M. and Schalley, C. A. and Haase, D. and Saak, W. and Lützen, A. and Gschwind, R. M. (2005) Controlling the Rate of Shuttling Motions in [2]Rotaxanes by Electrostatic Interactions: A Cation as Solvent-Tunable Brake. Organic & Biomolecular Chemistry 3 (15), pp. 2691-2700.

Henze, W. and Vyater, A. and Krause, N. and Gschwind, R. M. (2005) Influence of Tetrahydrofuran on Reactivity, Aggregation, and Aggregate Structure of Dimethylcuprates in Diethyl Ether. Journal of the American Chemical Society 127 (49), pp. 17335-17342.

Gschwind, R. M. (2005) Konzept gut, Umsetzung nicht ideal (Buchbesprechung aus „Structural Identification of Organic Compounds with Spectroscopic Techniques”). Nachrichten aus der Chemie 11, p. 1166.

Gschwind, R. M. (2005) NMR-Spektroskopie (Trendberichte 2004, Organische Chemie). Nachrichten aus der Chemie 53, p. 264.

Gschwind, R. M. (2005) Residual Dipolar Couplings - AValuable NMR Parameter for Small Organic Molecules. Angewandte Chemie International Edition 44 (30), pp. 4666-4668.

Gschwind, R. M. and Xie, X. and Rajamohanan, P. R. (2004) Gs-HSQC-NOESY versus gs-NOESY-HSQC experiments: Signal attenuation due to diffusion; application to symmetrical molecules. Magnetic Resonance in Chemistry 42 (3), pp. 308-312.

Gschwind, R. M. and Armbrüster, M. and Zubrzycki, I. Z. (2004) NMR detection of intermolecular NH×××OP hydrogen bonds between guanidinium protons and bisposphonate moieties in an artificial arginine receptor. Journal of the American Chemical Society 126 (33), pp. 10228-10229.

Gschwind, R. M. (2004) NMR-Spektroskopie (Trendberichte 2003, Organische Chemie). Nachrichten aus der Chemie 52, pp. 278-279.

Xie, X. and Auel, C. and Henze, W. and Gschwind, R. M. (2003) Dimethyl- and Bis[(trimethylsilyl)methyl]cuprates Show Aggregates higer than Dimers in Diethyl Ether: Molecular Diffusion Studies by PFG NMR and Aggregation-Reactivity Correlations. Journal of the American Chemical Society 125 (6), pp. 1595-1601.

Raab, V. and Kipke, J. and Gschwind, R. M. and Sundermeyer, J. (2002) 1,8-Bis(tetramethylguanidino)naphtalene (TMGN): a new superbasic and kinetically active „proton sponge. Chemistry - A European Journal 8 (7), pp. 1682-1693.

Jennemann, R. and Geyer, R. and Sandhoff, R. and Gschwind, R. M. and Levery, S. B. and Groene, H. J. and Wiegandt, H. (2001) Glycoinositolphosphosphingolipids, basidiolipids, of higher mushrooms. European Journal of Biochemistry 268 (5), pp. 1190-1205.

Gschwind, R. M. (2001) High-Resolution NMR Techniques in Organic Chemistry (Buchrezension). Angewandte Chemie International Edition 40 (14), pp. 2719-2720.

Hintz, M. and Reichenberg, A. and Altincicek, B. and Bahr, U. and Gschwind, R. M. and Kollas, A. and Beck, E. and Wiesner, J. and Eberl, M. and Jomaa, H. (2001) Identification of 4-hydroxy-3-methyl-but-2-enyl pyrophosphate as a major activator for human gamma delta T cells in Escherichia coli. FEBS Letters 509 (2), pp. 317-322.

Gschwind, R. M. and Xie, X. and Rajamohanan, P. R. and Auel, C. and Boche, G. (2001) Me(2)CuLi*LiCN in diethyl ether prefers a homodimeric core structure [Me(2)CuLi](2) and not a heterodimeric one [Me(2)CuLi*LiCN]: (1)H, (6)Li HOE and (1)H, (1)H NOE studies by NMR. Journal of the American Chemical Society 123 (30), pp. 7299-7304.

Hoffmann, R. W. and Müller, M. and Menzel, K. and Gschwind, R. M. and Schwerdtfeger, P. and Malkina, O. L. and Malkin, V.G. (2001) Reaction of Iodoform and Isopropyl Grignard Reagent Revisited. Organometallics 20 (25), pp. 5310-5313.

Gschwind, R. M. and Rajamohanan, P. R. and John, M. and Boche, G. (2000) Direct Insight into the Ion Pair Equilibria of Lithium Organocuprates by 1H,6Li HOESY Experiments. Organometallics 19 (15), pp. 2868-2873.

John, M. and Auel, C. and Behrens, C. and Marsch, M. and Harms, K. and Bosold, F. and Gschwind, R. M. and Rajamohanan, P. R. and Boche, G. (2000) The relation between ion pair structures and reactivities of lithium cuprates. Chemistry - A European Journal 6 (16), pp. 3060-3068.

Laaziri, H. and Bromm, L. O. and Lhermite, F. and Gschwind, R. M. and Knochel, P. (1999) A New Highly Stereoselective Rearrangement of Acyclic Tertiary Organoboranes: An Example of Highly Stereoselective Remote C-H Activation. Journal of the American Chemical Society 121 (29), pp. 6940-6941.

Gschwind, R. M. and Schlecht, S. (1999) A eta2-triflate (OTf) intermediate in the solution dynamics of PtMe3(OTf)*TMEDA: the windscreen-wiper process revisited. Dalton Transactions (11), pp. 1891-1895.

Gschwind, R. M. and Kessler, H. and Gemmecker, G. (1999) A new multi-quantum version of the HBHA(CBCACO)NH experiment with enhanced sensitivity for partially deuterated samples. Journal of Magnetic Resonance 137 (1), pp. 285-288.

Jennemann, R. and Bauer, B. L. and Bertalanffy, H. and Geyer, R. and Gschwind, R. M. and Selmer, T. and Wiegandt, H. (1999) Novel glycoinositolphosphosphingolipids, basidiolipids, from Agaricus. European Journal of Biochemistry 259 (1-2), pp. 331-338.

Gschwind, R. M. and Gemmecker, G. and Kessler, H. (1998) A spin labeled and highly resolved ed-H(CCO)NH-TOCSY experiment for the facilitated assignment of proton side chains in partially deuterated samples. Journal of Biomolecular NMR 11 (2), pp. 191-198.

Leutner, M. and Gschwind, R. M. and Liermann, J. and Schwarz, C. and Gemmecker, G. and Kessler, H. (1998) Automated backbone assignment of labeled proteins using the threshold accepting algorithm. Journal of Biomolecular NMR 11 (1), pp. 31-43.

Huenges, M. and Rölz, C. and Gschwind, R. M. and Peteranderl, R. and Berglechner, F. and Richter, G. and Bacher, A. and Kessler, H. and Gemmecker, G. (1998) Solution structure of the antitermination protein NusB of Escherichia coli: a novel all-helical fold for an RNA-binding protein. The EMBO Journal 17 (14), pp. 4092-4100.

Gschwind, R. M. and Gemmecker, G. and Leutner, M. and Kessler, H. and Gutknecht, R. and Lanz, R. and Flückiger, K. and Erni, B. (1997) Secondary structure of the IIB domain of Escherichia coli mannose transporter, a new fold in the class of alpha/beta twisted open-sheet structures. FEBS Letters 404 (1), pp. 45-50.

Berglechner, F. and Richter, G. and Fischer, M. and Bacher, A. and Gschwind, R. M. and Huenges, M. and Gemmecker, G. and Kessler, H. (1997) Studies on the NusB protein of Escherichia coli; Expression and determination of the secondary structure elements by multinuclear NMR spectroscopy. European Journal of Biochemistry 248 (2), pp. 338-346.

Book Section

Gärtner, T. and Gschwind, R. M. (2009) NMR of Organocopper Compounds. In: Rappoport, Z. and Marek, I., (eds.) The Chemistry of Organocopper Compounds. John Wiley & Sons Ltd., Chichester, England, pp. 163-215. ISBN 978-0-470-77296-6.

Thesis

Gschwind, R. M. (2001) Schwache intermolekulare Wechselwirkungen als strukturbestimmende Parameter - NMR-spektroskopische Strukturanalysen und Methodiken. Habilitation, Philipps-Universität.

Gschwind, R. M. (1997) Entwicklung und Anwendung NMR-Spektroskopischer Methoden zur Strukturaufklärung von Proteinen. PhD, Technische Universität München.

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