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Article

Dielmann, Fabian and Heindl, Claudia and Hastreiter, F. and Peresypkina, E. V. and Virovets, A. V. and Gschwind, R. M. and Scheer, M. (2014) A Nano-sized Supramolecule Beyond the Fullerene Topology. Angewandte Chemie International Edition, n/a-n/a.
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Neumeier, M. and Gschwind, R. M. (2014) Elongated Gilman Cuprates: The Key to Different Reactivities of Cyano- and Iodocuprates. Journal of the American Chemical Society 136 (15), pp. 5765-5772. Fulltext not available.

Hartmann, E. and Hammer, M. M. and Gschwind, R. M. (2013) Structures and Interligand Interaction Pattern of Phosphoramidite Pd Complexes by NMR: Modulations in Extended Interaction Surfaces as Stereoselection Mode of a Privileged Class of Ligands. Chemistry - A European Journal 19 (32), pp. 10551-10562. Fulltext not available.

Schober, K. and Hartmann, E. and Zhang, H. and Gschwind, R. M. (2010) 1H DOSY Spectra of Ligands for Highly Enantioselective Reactions - A Fast and Simple NMR Method to Optimize Catalytic Reaction Conditions. Angew. Chem. Int. Ed. 49 (15), pp. 2794-2797. Fulltext not available.

Kleinmaier, R. and Gschwind, R. M. (2010) Chemical Shift Assignment and Conformational Analysis of Monoalkylated Acylguanidines. Magn. Reson. Chem. 48 (9), pp. 687-684. Fulltext not available.

Kleinmaier, R. and Igel, P. and Keller, M. and Buschauer, Armin and Gschwind, R. M. (2010) Conformations, Conformational Preferences, and Conformational Exchange of N'-Substituted N-Acylguanidines: Intermolecular Interactions Hold the Key. J. Am. Chem. Soc. 132 (32), pp. 11223-11233. Fulltext not available.

Thaler, T. and Haag, B. and Gavryushin, A. and Schober, K. and Hartmann, E. and Gschwind, R. M. and Zipse, H. and Mayer, P. and Knochel, P. (2010) Highly diastereoselective Csp3–Csp2 Nis cross-coupling with 1,2-, 1,3- and 1,4-substituted cyclokylzinc compounds. Nature Chemistry 2 (2), pp. 125-130. Fulltext not available.

Brandl, Ferdinand and Kastner, Fritz and Gschwind, R. M. and Blunk, Torsten and Teßmar, Jörg and Göpferich, Achim (2010) Hydrogel-based drug delivery systems: Comparison of drug diffusivity and release kinetics. Journal of Controlled Release 142 (2), pp. 221-228. Fulltext not available.

Gärtner, T. and Yoshikai, N. and Neumeier, M. and Nakamura, E. and Gschwind, R. M. (2010) Ligand exchange reactions in Cu(III) complexes: mechanistic insights by combined NMR and DFT studies. Chem. Commun. 46 (25), pp. 4625-4626. Fulltext not available.

Ay, S. and Ziegert, R. E. and Zhang, H. and Nieger, M. and Rissanen, K. and Fink, K. and Kubas, A. and Gschwind, R. M. and Bräse, S. (2010) NMR-Spectroscopic and Solid-State Investigations of Cometal-Free Asymmetric Conjugate Addition: A Dinuclear Paracyclophaneimine Zinc Methyl Complex. J. Am. Chem. Soc. 132 (37), pp. 12899-12905. Fulltext not available.

Gschwind, R. M. (2010) NMR-Spektroskopie (Trendberichte 2009, Organische Chemie). Nachrichten aus der Chemie 58, pp. 280-281. Fulltext not available.

Schmid, M. B. and Zeitler, K. and Gschwind, R. M. (2010) The elusive enamine intermediate in proline-catalyzed aldol reactions: NMR detection, formation pathway, and stabilization trends. Angew. Chem. Int. Ed. 49 (29), pp. 4997-5003. Fulltext not available.

Zhang, H. and Kerssebaum, R. and Gschwind, R. M. (2009) Improved applicability of DOSY experiments by high resolution probes combined with gradient amplifiers of diffusion units. Magnetic Resonance Chemistry 47 (7), pp. 568-572. Fulltext not available.

Gschwind, R. M. (2009) NMR-Spektroskopie (Trendberichte 2008, Organische Chemie). Nachrichten aus der Chemie 57, pp. 262-263. Fulltext not available.

Schmid, M. and Fleischmann, M. and D´Elia, V. and Reiser, O. and Gronwald, W. and Gschwind, R. M. (2009) RDCs in Short Peptidic Foldamers: Combined Analyses of Backbone and Side Chain Conformations and Evaluation of Structure Coordinates of Rigid Unnatural Amino Acids. ChemBioChem 10 (3), pp. 440-444. Fulltext not available.

Kleinmaier, R. and Gschwind, R. M. (2009) Selective [15N.eta.2] labelling of an NG-propionylated arginine derivative. Journal of Labelled Compounds and Radiopharmaceuticals 52 (2), pp. 29-32. Fulltext not available.

Dem’yanov, P. I. and Polestshuk, P. M. and Gschwind, R. M. (2008) Hydrogen-bonding interactions in monomeric dimethylcuprates. A theoretical study. Journal of Molecular Structure THEOCHEM 861 (1-3), pp. 85-96. Fulltext not available.

Gschwind, R. M. (2008) NMR-Spektroskopie (Trendberichte 2007, Organische Chemie). Nachrichten aus der Chemie 56, p. 283. Fulltext not available.

Henze, W. and Gärtner, T. and Gschwind, R. M. (2008) Organocuprate Conjugate Addition: The Structural Features of Diastereomeric and Supramolecular p-Intermediates. Journal of the American Chemical Society 130 (41), pp. 13718-13726. Fulltext not available.

Gschwind, R. M. (2008) Organocuprates and Diamagnetic Copper Complexes: Structures and NMR Spectroscopic Structure Elucidation in Solution. Chemical Reviews 108 (8), pp. 3029-3053. Fulltext not available.

Dem’yanov, P. I. and Polestshuk, P. M. and Petrosyan, V. S. and Gschwind, R. M. (2008) Structure of (Me2Cu)Li • 3DME and its oligomers [(Me2Cu)Li • 3DME]n (n = 2-5): a theoretical study. Russian Chemical Bulletin 57 (3), pp. 480-492. Fulltext not available.

Schober, K. and Zhang, H. and Gschwind, R. M. (2008) Temperature-Dependent Interconversion of Phosphoramidite-Cu Complexes Detected by Combined Diffusion Studies, 31P NMR, and Low-Temperature NMR Spectroscopy. Journal of the American Chemical Society 130 (37), pp. 12310-12317. Fulltext not available.

Federwisch, G. and Kleinmaier, R. and Drettwan, D. and Gschwind, R. M. (2008) The H-Bonding Network of Acylguanidine Complexes: Combined Intermolecular 2hJH,P and 3hJN,P Scalar Couplings Provide an Insight into the Geometric Arrangement. Journal of the American Chemical Society 130 (50), pp. 16846-16847. Fulltext not available.

Zhang, H. and Gschwind, R. M. (2007) Influence of Copper Salts, Solvents, and Ligands on the Structures of Precatalytic Phosphoramidite Copper Complexes for Conjugate Addition Reactions. Chemistry - A European Journal 13 (23), pp. 6691-6700. Fulltext not available.

Gärtner, T. and Henze, W. and Gschwind, R. M. (2007) NMR-Detection of Cu(III) Intermediates in Substitution Reactions of Alkyl Halides with Gilman Cuprates. Journal of the American Chemical Society 129 (37), pp. 11362-11363. Fulltext not available.

Gschwind, R. M. (2007) NMR-Spektroskopie (Trendberichte 2006, Organische Chemie). Nachrichten aus der Chemie 55, pp. 273-274. Fulltext not available.

Brandl, F. and Henke, M. and Rothschenk, S. and Gschwind, R. M. and Breunig, M. and Tessmar, J and Goepferich, A. (2007) Poly(ethylene glycol) based hydrogels for intraocular applications. Advanced Engineering Materials 9 (12), pp. 1141-1149. Fulltext not available.

Dem'yanov, P. I. and Gschwind, R. M. (2006) Formation of Hydrogen Bonds in Complexes between Dimethylcuprate(I) Anion and Methane, Propane, or Dimethyl Ether. A Theoretical Study. Organometallics 25 (24), pp. 5709-5723. Fulltext not available.

Gschwind, R. M. (2006) NMR-Spektroskopie (Trendberichte 2005, Organische Chemie). Nachrichten aus der Chemie 54, p. 252. Fulltext not available.

Zhang, H. and Gschwind, R. M. (2006) Structure Identification of Precatalytic Phosphoramidite Complexes in Solution. Angewandte Chemie International Edition 45 (38), pp. 6391-6394. Fulltext not available.

Raab, M. and Schick, G. and Fondermann, M. D. and Henze, W. and Weymand, U. and Gschwind, R. M. and Fischer, K. and Schmidt, M. and Niecke, E. (2006) The First PH-Functionalized Polyphosphazene: A Liquid Macromolecule with Highly Flexible Backbone. Angewandte Chemie International Edition 45 (19), pp. 3083-3086. Fulltext not available.

Ghosh, P. and Federwisch, G. and Kogey, M. and Schalley, C. A. and Haase, D. and Saak, W. and Lützen, A. and Gschwind, R. M. (2005) Controlling the Rate of Shuttling Motions in [2]Rotaxanes by Electrostatic Interactions: A Cation as Solvent-Tunable Brake. Organic & Biomolecular Chemistry 3 (15), pp. 2691-2700. Fulltext not available.

Henze, W. and Vyater, A. and Krause, N. and Gschwind, R. M. (2005) Influence of Tetrahydrofuran on Reactivity, Aggregation, and Aggregate Structure of Dimethylcuprates in Diethyl Ether. Journal of the American Chemical Society 127 (49), pp. 17335-17342. Fulltext not available.

Gschwind, R. M. (2005) Konzept gut, Umsetzung nicht ideal (Buchbesprechung aus „Structural Identification of Organic Compounds with Spectroscopic Techniques”). Nachrichten aus der Chemie 11, p. 1166. Fulltext not available.

Gschwind, R. M. (2005) NMR-Spektroskopie (Trendberichte 2004, Organische Chemie). Nachrichten aus der Chemie 53, p. 264. Fulltext not available.

Gschwind, R. M. (2005) Residual Dipolar Couplings - AValuable NMR Parameter for Small Organic Molecules. Angewandte Chemie International Edition 44 (30), pp. 4666-4668. Fulltext not available.

Gschwind, R. M. and Xie, X. and Rajamohanan, P. R. (2004) Gs-HSQC-NOESY versus gs-NOESY-HSQC experiments: Signal attenuation due to diffusion; application to symmetrical molecules. Magnetic Resonance in Chemistry 42 (3), pp. 308-312. Fulltext not available.

Gschwind, R. M. and Armbrüster, M. and Zubrzycki, I. Z. (2004) NMR detection of intermolecular NH×××OP hydrogen bonds between guanidinium protons and bisposphonate moieties in an artificial arginine receptor. Journal of the American Chemical Society 126 (33), pp. 10228-10229. Fulltext not available.

Gschwind, R. M. (2004) NMR-Spektroskopie (Trendberichte 2003, Organische Chemie). Nachrichten aus der Chemie 52, pp. 278-279. Fulltext not available.

Xie, X. and Auel, C. and Henze, W. and Gschwind, R. M. (2003) Dimethyl- and Bis[(trimethylsilyl)methyl]cuprates Show Aggregates higer than Dimers in Diethyl Ether: Molecular Diffusion Studies by PFG NMR and Aggregation-Reactivity Correlations. Journal of the American Chemical Society 125 (6), pp. 1595-1601. Fulltext not available.

Raab, V. and Kipke, J. and Gschwind, R. M. and Sundermeyer, J. (2002) 1,8-Bis(tetramethylguanidino)naphtalene (TMGN): a new superbasic and kinetically active „proton sponge. Chemistry - A European Journal 8 (7), pp. 1682-1693. Fulltext not available.

Jennemann, R. and Geyer, R. and Sandhoff, R. and Gschwind, R. M. and Levery, S. B. and Groene, H. J. and Wiegandt, H. (2001) Glycoinositolphosphosphingolipids, basidiolipids, of higher mushrooms. European Journal of Biochemistry 268 (5), pp. 1190-1205. Fulltext not available.

Gschwind, R. M. (2001) High-Resolution NMR Techniques in Organic Chemistry (Buchrezension). Angewandte Chemie International Edition 40 (14), pp. 2719-2720. Fulltext not available.

Hintz, M. and Reichenberg, A. and Altincicek, B. and Bahr, U. and Gschwind, R. M. and Kollas, A. and Beck, E. and Wiesner, J. and Eberl, M. and Jomaa, H. (2001) Identification of 4-hydroxy-3-methyl-but-2-enyl pyrophosphate as a major activator for human gamma delta T cells in Escherichia coli. FEBS Letters 509 (2), pp. 317-322. Fulltext not available.

Gschwind, R. M. and Xie, X. and Rajamohanan, P. R. and Auel, C. and Boche, G. (2001) Me(2)CuLi*LiCN in diethyl ether prefers a homodimeric core structure [Me(2)CuLi](2) and not a heterodimeric one [Me(2)CuLi*LiCN]: (1)H, (6)Li HOE and (1)H, (1)H NOE studies by NMR. Journal of the American Chemical Society 123 (30), pp. 7299-7304. Fulltext not available.

Hoffmann, R. W. and Müller, M. and Menzel, K. and Gschwind, R. M. and Schwerdtfeger, P. and Malkina, O. L. and Malkin, V.G. (2001) Reaction of Iodoform and Isopropyl Grignard Reagent Revisited. Organometallics 20 (25), pp. 5310-5313. Fulltext not available.

Gschwind, R. M. and Rajamohanan, P. R. and John, M. and Boche, G. (2000) Direct Insight into the Ion Pair Equilibria of Lithium Organocuprates by 1H,6Li HOESY Experiments. Organometallics 19 (15), pp. 2868-2873. Fulltext not available.

John, M. and Auel, C. and Behrens, C. and Marsch, M. and Harms, K. and Bosold, F. and Gschwind, R. M. and Rajamohanan, P. R. and Boche, G. (2000) The relation between ion pair structures and reactivities of lithium cuprates. Chemistry - A European Journal 6 (16), pp. 3060-3068. Fulltext not available.

Laaziri, H. and Bromm, L. O. and Lhermite, F. and Gschwind, R. M. and Knochel, P. (1999) A New Highly Stereoselective Rearrangement of Acyclic Tertiary Organoboranes: An Example of Highly Stereoselective Remote C-H Activation. Journal of the American Chemical Society 121 (29), pp. 6940-6941. Fulltext not available.

Gschwind, R. M. and Schlecht, S. (1999) A eta2-triflate (OTf) intermediate in the solution dynamics of PtMe3(OTf)*TMEDA: the windscreen-wiper process revisited. Dalton Transactions (11), pp. 1891-1895. Fulltext not available.

Gschwind, R. M. and Kessler, H. and Gemmecker, G. (1999) A new multi-quantum version of the HBHA(CBCACO)NH experiment with enhanced sensitivity for partially deuterated samples. Journal of Magnetic Resonance 137 (1), pp. 285-288. Fulltext not available.

Jennemann, R. and Bauer, B. L. and Bertalanffy, H. and Geyer, R. and Gschwind, R. M. and Selmer, T. and Wiegandt, H. (1999) Novel glycoinositolphosphosphingolipids, basidiolipids, from Agaricus. European Journal of Biochemistry 259 (1-2), pp. 331-338. Fulltext not available.

Gschwind, R. M. and Gemmecker, G. and Kessler, H. (1998) A spin labeled and highly resolved ed-H(CCO)NH-TOCSY experiment for the facilitated assignment of proton side chains in partially deuterated samples. Journal of Biomolecular NMR 11 (2), pp. 191-198. Fulltext not available.

Leutner, M. and Gschwind, R. M. and Liermann, J. and Schwarz, C. and Gemmecker, G. and Kessler, H. (1998) Automated backbone assignment of labeled proteins using the threshold accepting algorithm. Journal of Biomolecular NMR 11 (1), pp. 31-43. Fulltext not available.

Huenges, M. and Rölz, C. and Gschwind, R. M. and Peteranderl, R. and Berglechner, F. and Richter, G. and Bacher, A. and Kessler, H. and Gemmecker, G. (1998) Solution structure of the antitermination protein NusB of Escherichia coli: a novel all-helical fold for an RNA-binding protein. The EMBO Journal 17 (14), pp. 4092-4100. Fulltext not available.

Gschwind, R. M. and Gemmecker, G. and Leutner, M. and Kessler, H. and Gutknecht, R. and Lanz, R. and Flückiger, K. and Erni, B. (1997) Secondary structure of the IIB domain of Escherichia coli mannose transporter, a new fold in the class of alpha/beta twisted open-sheet structures. FEBS Letters 404 (1), pp. 45-50. Fulltext not available.

Berglechner, F. and Richter, G. and Fischer, M. and Bacher, A. and Gschwind, R. M. and Huenges, M. and Gemmecker, G. and Kessler, H. (1997) Studies on the NusB protein of Escherichia coli; Expression and determination of the secondary structure elements by multinuclear NMR spectroscopy. European Journal of Biochemistry 248 (2), pp. 338-346. Fulltext not available.

Book Section

Gärtner, T. and Gschwind, R. M. (2009) NMR of Organocopper Compounds. In: Rappoport, Z. and Marek, I., (eds.) The Chemistry of Organocopper Compounds. John Wiley & Sons Ltd., Chichester, England, pp. 163-215. ISBN 978-0-470-77296-6. Fulltext not available.

Thesis

Gschwind, R. M. (2001) Schwache intermolekulare Wechselwirkungen als strukturbestimmende Parameter - NMR-spektroskopische Strukturanalysen und Methodiken. Habilitation, Philipps-Universität. Fulltext not available.

Gschwind, R. M. (1997) Entwicklung und Anwendung NMR-Spektroskopischer Methoden zur Strukturaufklärung von Proteinen. PhD, Technische Universität München. Fulltext not available.

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