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Article

Dielmann, Fabian and Heindl, Claudia and Hastreiter, F. and Peresypkina, E. V. and Virovets, A. V. and Gschwind, R. M. and Scheer, M. (2014) A Nano-sized Supramolecule Beyond the Fullerene Topology. Angewandte Chemie International Edition, pp. 13605-13608.
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Neumeier, M. and Gschwind, R. M. (2014) Elongated Gilman Cuprates: The Key to Different Reactivities of Cyano- and Iodocuprates. Journal of the American Chemical Society 136 (15), pp. 5765-5772. Volltext nicht vorhanden.

Hartmann, E. and Hammer, M. M. and Gschwind, R. M. (2013) Structures and Interligand Interaction Pattern of Phosphoramidite Pd Complexes by NMR: Modulations in Extended Interaction Surfaces as Stereoselection Mode of a Privileged Class of Ligands. Chemistry - A European Journal 19 (32), pp. 10551-10562. Volltext nicht vorhanden.

Schober, K. and Hartmann, E. and Zhang, H. and Gschwind, R. M. (2010) 1H DOSY Spectra of Ligands for Highly Enantioselective Reactions - A Fast and Simple NMR Method to Optimize Catalytic Reaction Conditions. Angew. Chem. Int. Ed. 49 (15), pp. 2794-2797. Volltext nicht vorhanden.

Kleinmaier, R. and Gschwind, R. M. (2010) Chemical Shift Assignment and Conformational Analysis of Monoalkylated Acylguanidines. Magn. Reson. Chem. 48 (9), pp. 687-684. Volltext nicht vorhanden.

Kleinmaier, R. and Igel, P. and Keller, M. and Buschauer, Armin and Gschwind, R. M. (2010) Conformations, Conformational Preferences, and Conformational Exchange of N'-Substituted N-Acylguanidines: Intermolecular Interactions Hold the Key. J. Am. Chem. Soc. 132 (32), pp. 11223-11233. Volltext nicht vorhanden.

Thaler, T. and Haag, B. and Gavryushin, A. and Schober, K. and Hartmann, E. and Gschwind, R. M. and Zipse, H. and Mayer, P. and Knochel, P. (2010) Highly diastereoselective Csp3–Csp2 Nis cross-coupling with 1,2-, 1,3- and 1,4-substituted cyclokylzinc compounds. Nature Chemistry 2 (2), pp. 125-130. Volltext nicht vorhanden.

Brandl, Ferdinand and Kastner, Fritz and Gschwind, R. M. and Blunk, Torsten and Teßmar, Jörg and Göpferich, Achim (2010) Hydrogel-based drug delivery systems: Comparison of drug diffusivity and release kinetics. Journal of Controlled Release 142 (2), pp. 221-228. Volltext nicht vorhanden.

Gärtner, T. and Yoshikai, N. and Neumeier, M. and Nakamura, E. and Gschwind, R. M. (2010) Ligand exchange reactions in Cu(III) complexes: mechanistic insights by combined NMR and DFT studies. Chem. Commun. 46 (25), pp. 4625-4626. Volltext nicht vorhanden.

Ay, S. and Ziegert, R. E. and Zhang, H. and Nieger, M. and Rissanen, K. and Fink, K. and Kubas, A. and Gschwind, R. M. and Bräse, S. (2010) NMR-Spectroscopic and Solid-State Investigations of Cometal-Free Asymmetric Conjugate Addition: A Dinuclear Paracyclophaneimine Zinc Methyl Complex. J. Am. Chem. Soc. 132 (37), pp. 12899-12905. Volltext nicht vorhanden.

Gschwind, R. M. (2010) NMR-Spektroskopie (Trendberichte 2009, Organische Chemie). Nachrichten aus der Chemie 58, pp. 280-281. Volltext nicht vorhanden.

Schmid, M. B. and Zeitler, K. and Gschwind, R. M. (2010) The elusive enamine intermediate in proline-catalyzed aldol reactions: NMR detection, formation pathway, and stabilization trends. Angew. Chem. Int. Ed. 49 (29), pp. 4997-5003. Volltext nicht vorhanden.

Zhang, H. and Kerssebaum, R. and Gschwind, R. M. (2009) Improved applicability of DOSY experiments by high resolution probes combined with gradient amplifiers of diffusion units. Magnetic Resonance Chemistry 47 (7), pp. 568-572. Volltext nicht vorhanden.

Gschwind, R. M. (2009) NMR-Spektroskopie (Trendberichte 2008, Organische Chemie). Nachrichten aus der Chemie 57, pp. 262-263. Volltext nicht vorhanden.

Schmid, M. and Fleischmann, M. and D´Elia, V. and Reiser, O. and Gronwald, W. and Gschwind, R. M. (2009) RDCs in Short Peptidic Foldamers: Combined Analyses of Backbone and Side Chain Conformations and Evaluation of Structure Coordinates of Rigid Unnatural Amino Acids. ChemBioChem 10 (3), pp. 440-444. Volltext nicht vorhanden.

Kleinmaier, R. and Gschwind, R. M. (2009) Selective [15N.eta.2] labelling of an NG-propionylated arginine derivative. Journal of Labelled Compounds and Radiopharmaceuticals 52 (2), pp. 29-32. Volltext nicht vorhanden.

Dem’yanov, P. I. and Polestshuk, P. M. and Gschwind, R. M. (2008) Hydrogen-bonding interactions in monomeric dimethylcuprates. A theoretical study. Journal of Molecular Structure THEOCHEM 861 (1-3), pp. 85-96. Volltext nicht vorhanden.

Gschwind, R. M. (2008) NMR-Spektroskopie (Trendberichte 2007, Organische Chemie). Nachrichten aus der Chemie 56, p. 283. Volltext nicht vorhanden.

Henze, W. and Gärtner, T. and Gschwind, R. M. (2008) Organocuprate Conjugate Addition: The Structural Features of Diastereomeric and Supramolecular p-Intermediates. Journal of the American Chemical Society 130 (41), pp. 13718-13726. Volltext nicht vorhanden.

Gschwind, R. M. (2008) Organocuprates and Diamagnetic Copper Complexes: Structures and NMR Spectroscopic Structure Elucidation in Solution. Chemical Reviews 108 (8), pp. 3029-3053. Volltext nicht vorhanden.

Dem’yanov, P. I. and Polestshuk, P. M. and Petrosyan, V. S. and Gschwind, R. M. (2008) Structure of (Me2Cu)Li • 3DME and its oligomers [(Me2Cu)Li • 3DME]n (n = 2-5): a theoretical study. Russian Chemical Bulletin 57 (3), pp. 480-492. Volltext nicht vorhanden.

Schober, K. and Zhang, H. and Gschwind, R. M. (2008) Temperature-Dependent Interconversion of Phosphoramidite-Cu Complexes Detected by Combined Diffusion Studies, 31P NMR, and Low-Temperature NMR Spectroscopy. Journal of the American Chemical Society 130 (37), pp. 12310-12317. Volltext nicht vorhanden.

Federwisch, G. and Kleinmaier, R. and Drettwan, D. and Gschwind, R. M. (2008) The H-Bonding Network of Acylguanidine Complexes: Combined Intermolecular 2hJH,P and 3hJN,P Scalar Couplings Provide an Insight into the Geometric Arrangement. Journal of the American Chemical Society 130 (50), pp. 16846-16847. Volltext nicht vorhanden.

Zhang, H. and Gschwind, R. M. (2007) Influence of Copper Salts, Solvents, and Ligands on the Structures of Precatalytic Phosphoramidite Copper Complexes for Conjugate Addition Reactions. Chemistry - A European Journal 13 (23), pp. 6691-6700. Volltext nicht vorhanden.

Gärtner, T. and Henze, W. and Gschwind, R. M. (2007) NMR-Detection of Cu(III) Intermediates in Substitution Reactions of Alkyl Halides with Gilman Cuprates. Journal of the American Chemical Society 129 (37), pp. 11362-11363. Volltext nicht vorhanden.

Gschwind, R. M. (2007) NMR-Spektroskopie (Trendberichte 2006, Organische Chemie). Nachrichten aus der Chemie 55, pp. 273-274. Volltext nicht vorhanden.

Brandl, F. and Henke, M. and Rothschenk, S. and Gschwind, R. M. and Breunig, M. and Tessmar, J and Goepferich, A. (2007) Poly(ethylene glycol) based hydrogels for intraocular applications. Advanced Engineering Materials 9 (12), pp. 1141-1149. Volltext nicht vorhanden.

Dem'yanov, P. I. and Gschwind, R. M. (2006) Formation of Hydrogen Bonds in Complexes between Dimethylcuprate(I) Anion and Methane, Propane, or Dimethyl Ether. A Theoretical Study. Organometallics 25 (24), pp. 5709-5723. Volltext nicht vorhanden.

Gschwind, R. M. (2006) NMR-Spektroskopie (Trendberichte 2005, Organische Chemie). Nachrichten aus der Chemie 54, p. 252. Volltext nicht vorhanden.

Zhang, H. and Gschwind, R. M. (2006) Structure Identification of Precatalytic Phosphoramidite Complexes in Solution. Angewandte Chemie International Edition 45 (38), pp. 6391-6394. Volltext nicht vorhanden.

Raab, M. and Schick, G. and Fondermann, M. D. and Henze, W. and Weymand, U. and Gschwind, R. M. and Fischer, K. and Schmidt, M. and Niecke, E. (2006) The First PH-Functionalized Polyphosphazene: A Liquid Macromolecule with Highly Flexible Backbone. Angewandte Chemie International Edition 45 (19), pp. 3083-3086. Volltext nicht vorhanden.

Ghosh, P. and Federwisch, G. and Kogey, M. and Schalley, C. A. and Haase, D. and Saak, W. and Lützen, A. and Gschwind, R. M. (2005) Controlling the Rate of Shuttling Motions in [2]Rotaxanes by Electrostatic Interactions: A Cation as Solvent-Tunable Brake. Organic & Biomolecular Chemistry 3 (15), pp. 2691-2700. Volltext nicht vorhanden.

Henze, W. and Vyater, A. and Krause, N. and Gschwind, R. M. (2005) Influence of Tetrahydrofuran on Reactivity, Aggregation, and Aggregate Structure of Dimethylcuprates in Diethyl Ether. Journal of the American Chemical Society 127 (49), pp. 17335-17342. Volltext nicht vorhanden.

Gschwind, R. M. (2005) Konzept gut, Umsetzung nicht ideal (Buchbesprechung aus „Structural Identification of Organic Compounds with Spectroscopic Techniques”). Nachrichten aus der Chemie 11, p. 1166. Volltext nicht vorhanden.

Gschwind, R. M. (2005) NMR-Spektroskopie (Trendberichte 2004, Organische Chemie). Nachrichten aus der Chemie 53, p. 264. Volltext nicht vorhanden.

Gschwind, R. M. (2005) Residual Dipolar Couplings - AValuable NMR Parameter for Small Organic Molecules. Angewandte Chemie International Edition 44 (30), pp. 4666-4668. Volltext nicht vorhanden.

Gschwind, R. M. and Xie, X. and Rajamohanan, P. R. (2004) Gs-HSQC-NOESY versus gs-NOESY-HSQC experiments: Signal attenuation due to diffusion; application to symmetrical molecules. Magnetic Resonance in Chemistry 42 (3), pp. 308-312. Volltext nicht vorhanden.

Gschwind, R. M. and Armbrüster, M. and Zubrzycki, I. Z. (2004) NMR detection of intermolecular NH×××OP hydrogen bonds between guanidinium protons and bisposphonate moieties in an artificial arginine receptor. Journal of the American Chemical Society 126 (33), pp. 10228-10229. Volltext nicht vorhanden.

Gschwind, R. M. (2004) NMR-Spektroskopie (Trendberichte 2003, Organische Chemie). Nachrichten aus der Chemie 52, pp. 278-279. Volltext nicht vorhanden.

Xie, X. and Auel, C. and Henze, W. and Gschwind, R. M. (2003) Dimethyl- and Bis[(trimethylsilyl)methyl]cuprates Show Aggregates higer than Dimers in Diethyl Ether: Molecular Diffusion Studies by PFG NMR and Aggregation-Reactivity Correlations. Journal of the American Chemical Society 125 (6), pp. 1595-1601. Volltext nicht vorhanden.

Raab, V. and Kipke, J. and Gschwind, R. M. and Sundermeyer, J. (2002) 1,8-Bis(tetramethylguanidino)naphtalene (TMGN): a new superbasic and kinetically active „proton sponge. Chemistry - A European Journal 8 (7), pp. 1682-1693. Volltext nicht vorhanden.

Jennemann, R. and Geyer, R. and Sandhoff, R. and Gschwind, R. M. and Levery, S. B. and Groene, H. J. and Wiegandt, H. (2001) Glycoinositolphosphosphingolipids, basidiolipids, of higher mushrooms. European Journal of Biochemistry 268 (5), pp. 1190-1205. Volltext nicht vorhanden.

Gschwind, R. M. (2001) High-Resolution NMR Techniques in Organic Chemistry (Buchrezension). Angewandte Chemie International Edition 40 (14), pp. 2719-2720. Volltext nicht vorhanden.

Hintz, M. and Reichenberg, A. and Altincicek, B. and Bahr, U. and Gschwind, R. M. and Kollas, A. and Beck, E. and Wiesner, J. and Eberl, M. and Jomaa, H. (2001) Identification of 4-hydroxy-3-methyl-but-2-enyl pyrophosphate as a major activator for human gamma delta T cells in Escherichia coli. FEBS Letters 509 (2), pp. 317-322. Volltext nicht vorhanden.

Gschwind, R. M. and Xie, X. and Rajamohanan, P. R. and Auel, C. and Boche, G. (2001) Me(2)CuLi*LiCN in diethyl ether prefers a homodimeric core structure [Me(2)CuLi](2) and not a heterodimeric one [Me(2)CuLi*LiCN]: (1)H, (6)Li HOE and (1)H, (1)H NOE studies by NMR. Journal of the American Chemical Society 123 (30), pp. 7299-7304. Volltext nicht vorhanden.

Hoffmann, R. W. and Müller, M. and Menzel, K. and Gschwind, R. M. and Schwerdtfeger, P. and Malkina, O. L. and Malkin, V.G. (2001) Reaction of Iodoform and Isopropyl Grignard Reagent Revisited. Organometallics 20 (25), pp. 5310-5313. Volltext nicht vorhanden.

Gschwind, R. M. and Rajamohanan, P. R. and John, M. and Boche, G. (2000) Direct Insight into the Ion Pair Equilibria of Lithium Organocuprates by 1H,6Li HOESY Experiments. Organometallics 19 (15), pp. 2868-2873. Volltext nicht vorhanden.

John, M. and Auel, C. and Behrens, C. and Marsch, M. and Harms, K. and Bosold, F. and Gschwind, R. M. and Rajamohanan, P. R. and Boche, G. (2000) The relation between ion pair structures and reactivities of lithium cuprates. Chemistry - A European Journal 6 (16), pp. 3060-3068. Volltext nicht vorhanden.

Laaziri, H. and Bromm, L. O. and Lhermite, F. and Gschwind, R. M. and Knochel, P. (1999) A New Highly Stereoselective Rearrangement of Acyclic Tertiary Organoboranes: An Example of Highly Stereoselective Remote C-H Activation. Journal of the American Chemical Society 121 (29), pp. 6940-6941. Volltext nicht vorhanden.

Gschwind, R. M. and Schlecht, S. (1999) A eta2-triflate (OTf) intermediate in the solution dynamics of PtMe3(OTf)*TMEDA: the windscreen-wiper process revisited. Dalton Transactions (11), pp. 1891-1895. Volltext nicht vorhanden.

Gschwind, R. M. and Kessler, H. and Gemmecker, G. (1999) A new multi-quantum version of the HBHA(CBCACO)NH experiment with enhanced sensitivity for partially deuterated samples. Journal of Magnetic Resonance 137 (1), pp. 285-288. Volltext nicht vorhanden.

Jennemann, R. and Bauer, B. L. and Bertalanffy, H. and Geyer, R. and Gschwind, R. M. and Selmer, T. and Wiegandt, H. (1999) Novel glycoinositolphosphosphingolipids, basidiolipids, from Agaricus. European Journal of Biochemistry 259 (1-2), pp. 331-338. Volltext nicht vorhanden.

Gschwind, R. M. and Gemmecker, G. and Kessler, H. (1998) A spin labeled and highly resolved ed-H(CCO)NH-TOCSY experiment for the facilitated assignment of proton side chains in partially deuterated samples. Journal of Biomolecular NMR 11 (2), pp. 191-198. Volltext nicht vorhanden.

Leutner, M. and Gschwind, R. M. and Liermann, J. and Schwarz, C. and Gemmecker, G. and Kessler, H. (1998) Automated backbone assignment of labeled proteins using the threshold accepting algorithm. Journal of Biomolecular NMR 11 (1), pp. 31-43. Volltext nicht vorhanden.

Huenges, M. and Rölz, C. and Gschwind, R. M. and Peteranderl, R. and Berglechner, F. and Richter, G. and Bacher, A. and Kessler, H. and Gemmecker, G. (1998) Solution structure of the antitermination protein NusB of Escherichia coli: a novel all-helical fold for an RNA-binding protein. The EMBO Journal 17 (14), pp. 4092-4100. Volltext nicht vorhanden.

Gschwind, R. M. and Gemmecker, G. and Leutner, M. and Kessler, H. and Gutknecht, R. and Lanz, R. and Flückiger, K. and Erni, B. (1997) Secondary structure of the IIB domain of Escherichia coli mannose transporter, a new fold in the class of alpha/beta twisted open-sheet structures. FEBS Letters 404 (1), pp. 45-50. Volltext nicht vorhanden.

Berglechner, F. and Richter, G. and Fischer, M. and Bacher, A. and Gschwind, R. M. and Huenges, M. and Gemmecker, G. and Kessler, H. (1997) Studies on the NusB protein of Escherichia coli; Expression and determination of the secondary structure elements by multinuclear NMR spectroscopy. European Journal of Biochemistry 248 (2), pp. 338-346. Volltext nicht vorhanden.

Book Section

Gärtner, T. and Gschwind, R. M. (2009) NMR of Organocopper Compounds. In: Rappoport, Z. and Marek, I., (eds.) The Chemistry of Organocopper Compounds. John Wiley & Sons Ltd., Chichester, England, pp. 163-215. ISBN 978-0-470-77296-6. Volltext nicht vorhanden.

Thesis

Gschwind, R. M. (2001) Schwache intermolekulare Wechselwirkungen als strukturbestimmende Parameter - NMR-spektroskopische Strukturanalysen und Methodiken. Habilitation, Philipps-Universität. Volltext nicht vorhanden.

Gschwind, R. M. (1997) Entwicklung und Anwendung NMR-Spektroskopischer Methoden zur Strukturaufklärung von Proteinen. PhD, Technische Universität München. Volltext nicht vorhanden.

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